No, by our current understanding there is no length smaller than a Planck length, and any distance must therefore be divisible by an integer. That is, the length is made up of discrete quanta. Pi, or any other irrational number, is by definition not divisible by an integer, or it would be a ratio, making it rational. This has nothing to do with the accuracy or precision of our measures.
I’ll never not post this when people talk about Kirk this way: Freshly Remember’d: Kirk Drift